A baguette:  
First, make sure it's fresh from the day. Prefer to
buy bread directly from a bakery rather than from a reseller, because
bakeries will usually clearly mark day-old bread. The crust should be
crunchy and brittle, not soft. The color should be a light golden
brown. The packaging, if any, should be made of paper and let the
baguette breathe; anything else will cause the baguette to be soft and
chewy instead of crunchy. If ingredients are listed, they should
consist only of flour, yeast, salt and water.
A pastry:  
First, make sure it's fresh from the day. While most
pastries can last 2-3 days, their taste and texture steadily decline
during that time. Most pastry shops will clearly mark day old
pastries, but resellers don't usually do that. Pastries that are
day-old or more have a drier, more tired look. Second, most of
the time, you can trust that the taste of the pastry will match its
looks; pastry chefs that can make great tasting cakes also have the
skills to make them beautiful, so a good tip is to prefer stores that
make good looking pastries.
Some chocolates:  
There are few rules regarding buying chocolates. One
is to avoid dull looking chocolates, as this may indicate they are old
(though still edible). Chocolates can be kept anywhere from a couple
of weeks to a few months, depending on the centers they contain and
the preservatives that were used. As a rule, the shorter the life of a
chocolate, the fresher it will be and the least preservatives it will
contain; chocolates from larger chains are often made to have a long
shelf life. Passed that, the main factor is of course your own taste;
you can always buy just a couple of chocolates when you visit a new
store, and return to buy more later if you liked them.
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